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Continuous pin-hole free FA0.78Cs0.22Pb(I0.85Br0.15)3 flms are deposited by gas-assisted slot-die printing under ambient conditions using DMF/DMSO based ink containing Formamdinium Acetate additive. Using a binary solvent mixture of DMF and DMSO is effective in eliminating the non-perovskite phase that occurs when DMF alone is used. Print-speed, gas fow rate and chuck temperature are optimized to realize homogeneous flms with constant bandgap (1.63 eV) over large substrates (2″×4″). The perovskite flms prepared using two solvents DMF and DMF: DMSO (9:1) were incorporated in single junction devices. The resulting devices show improved fll factor with improved power conversion effciency.more » « less
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Halim, Md Abdul; Karmakar, Subrata; Hamid, Md Abdul; Chandan, Chironjib_Singha Samanta; Rahaman, Imteaz; Urena, Michael E; Haque, Ariful; Chen, Maggie Yihong; Rhodes, Christopher P; Beall, Gary W (, ACS Applied Materials & Interfaces)
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Howlader, Chandan; Hasan, Mehedhi; Zakhidov, Alex; Chen, Maggie Yihong (, Optical Materials)null (Ed.)
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